THERMALLY-OPTICALLY-THERMALLY STIMULATED LUMINESCENCE

  • Dianabasi Akpan University of Uyo, Uyo
  • Sunday Ekpo University of Uyo, Uyo
  • Christopher Effiong University of Uyo, Uyo
  • Mfoniso Aka University of Uyo, Uyo
Keywords: Stimulation, Model, Thermally, Optically, Luminescence

Abstract

A three-stage energy band model was studied. The model consists of electrons thermally stimulated from the ground state to the first excited state, after which they were optically stimulated into the second excited state and they were finally stimulated thermally into the conduction band. A set of simultaneous differential equations was generated from the models and three assumed conditions were applied to this model, which they were solved analytically and analytical expressions were obtained. The same set of simultaneous equations were solved numerically using ode 15s MATLAB solver. When considering first-order peaks, the kinetic parameters obtained were found to be in good agreement with the analytical expressions. But when considering non first-order peaks, the kinetic parameters obtained numerically were not in good agreement with the analytical expressions and explanations had been given. Second-order peaks could not be obtained despite careful selection of the kinetic parameters because the traps were quickly saturated and the quasi- equilibrium conditions assumed could no longer be satisfied. The stability of the excited TA-OSL signals produced by the model was also studied. The real stability of the excited TA-OSL signals produced by this model was found to be about 46 million years.

Downloads

Download data is not yet available.

Author Biographies

Dianabasi Akpan, University of Uyo, Uyo

Department of Physics

Sunday Ekpo, University of Uyo, Uyo

Department of Physics

Christopher Effiong, University of Uyo, Uyo

Department of Geoscience

Mfoniso Aka, University of Uyo, Uyo

Department of Physics

References

[1] E. Bulur, “An alternative technique for optically stimulated luminescence,” in Radiat. Meas. 26, 701-709, 1996.
[2] D.J. Huntley, D.I. Godfrey-Smith, & M.L.W. Thewalt, “Optical dating of sediments,” in Nature 313, 105-107, 1985.
[3] S.W.S. McKeever, “Thermoluminescence of solids,” Cambridge University Press, USA, PP.374, 1985.
[4] R. Chen, “Theory of thermoluminescence and related phenomena,” in World Scientific Publishing Co. Pvt. Ltd.
[5] M. Zahedifar, S. Harooni & E. Sadeghi, “Thermoluminescence kinetic analysis of quartz using an improved general mode for exponential distribution of activation energies,” in Nuccl. Instrum. Methods A 654, 569 – 574, 2011.
[6] N. D. Sang, “Estimate half-life of thermoluminescence signals according to the different models by using Python,” in Journal of Taibah University for science. 15 (1), 599-608, 2021.
[7] R. Chen, & V. Pagonis, “Modeling TL-like thermally assisted optically stimulated luminescence (TA-OSL),” in Radiat. Meas.56, 6-12, 2013.
[8] R. Chen, & V. Pagonis, “The role of simulations in the study of thermoluminescence (TL),” Radiat. Meas. 1-7, 2014.
[9] R. Chen, & V. Pagonis, “Study of the stability of the TL and OSL signals,” Radiat. Meas. 81, 192-197, 2015.
[10] N. A. Spooner, “The anomalous fading of infrared-stimulated luminescence from feldspars,” Radiat. Meas. 23, 625-632, 1994.
[11] R. Chen & S.W.S. Mckeever, “Theory of thermoluminescence and related phenomena,” in World Scientific, Singapore. Pages 1-146, 1997.
[12] J. M. Kalita & M. L. Chithambo, “Themoluminescence of α-Al203:C,Mg: Kinetic analysis of the main glow peak,” Journal of Luminescence 182, 177-182, 2017.
[13] G. S. Polymeris & K. George, “Advances in physics and applications of optically and thermally stimulated luminescence,” Pages 131-171, 2019.
[14] D. Akpan, A. Ekanem, & B. Ebiang, “A Three-stage thermal Stimulation of thermoluminescence (TL),” in Journal of Luminescence and Applications. 4(1), 10-29, 2017.
[15] G. Hutt, I. Jaek & J. Tchonka, “Optical dating: k-feldspars optical response stimulation spectra,” in Quarter. Sci. Rev. 7, 381-385, 1988.
[16] A. Halperin & A.A. Braner, “Evaluation of thermal activation energies from glow curves,” in Physiol. Rev. 117, 408-415, 1960.
[17] R. Chen, “On the calculation of activation energies and frequency factors from glow curves,” in J. Appl. Phys. 40, 570-585, 1969.
[18] R. Chen, J.L. Lawless & V. Pagonis, “Two-stage thermal stimulation of thermoluminescence,” in Radiat. Meas. 47, 809-813, 2012.
[19] J. T. Randall & M. H. F. Wilkins, “Phosphorescence and electron traps.The study of traps distributions,” in Proc. Roy. Soc. Lond. A 184, 366, 1945.
[20] G. F.J. Garlick & A. F. Gibson, “The electron trap mechanism of luminescence in sulphide and silicate phosphors,” in Proc. Phys. Soc. 60, 574, 1948.
[21] J. L. Lawless, R. Chen & V. Pagonis, “A model for explaining the inability of exciting thermoluminescence (TL) peaks in certain low temperature ranges,” in Radiat. Meas. 145, 106610, 2021.
[22] A.G. Wintle, “Thermal quenching of thermoluminescence in quartz,” in Geophys. J.R. Astr. Soc. 41, 107-113, 1975.
Published
2023-06-07
How to Cite
Akpan, D., Ekpo, S., Effiong, C., & Aka, M. (2023). THERMALLY-OPTICALLY-THERMALLY STIMULATED LUMINESCENCE. IJRDO-Journal of Applied Science, 9(6), 1-10. https://doi.org/10.53555/as.v9i6.4773